Trip was revealed to have caught it in BW34. He used it to try and catch a wild Palpitoad and later in the episode it battled Ash's Tepig. Iris has also been shown to be scared of Ice- types so she has terrified look on her face whenever she sees Vanillite. Its known moves are Icicle Spear and Ice Beam. 
Trip's Pokémon | |
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On hand | |
Trip |