Phione is a water-type Pokémon who appeared in the anime.
In Hold the Phione, this Phione falls in love with Dawn's Buneary and tries to show it, only for Buneary to push it aside as it still has a crush on Ash's Pikachu. This upsets Phione, and it challenges Pikachu, but Buneary steps in to battle Phione instead. Buneary ultimately wins, leaving the lovestruck Pokémon heart-broken. Before it leaves though, it helps Buneary get rid of Team Rocket.