Scolipede

Scolipede is / Pokémon from Generation V. It is the evolved form of Whirlipede and the second evolved form of Venipede. The evolution chain for Scolipede's family is that Venipede evolves into Whirlipede at Level 22, then into Scolipede at Level 30. Scolipede is modeled after a centipede. It has a counterpart like a "Caterpie/Weedle" situation named Leavanny.

In the anime
A Scolipede appears in Pokémon Best Wishes episode 9 and kidnaps Iris' Axew and ends up battling Iris' Excadrill.

Trivia

 * Although centipedes have a hundred legs and walk on most of them most of the time, Scolipede seems to be quadrapedal.
 * Scolipede may have been loosley based on Arthropluera, a prehistoric relative of centipedes and millipedes, that could grow to two and a half metres in length. This also ties in with Scolipede's length of 2.5m. However, Arthropluera lived in swamps, as opposed to Venipede and Whirlipede-Scolipede's pre-evolutions-living in forests.
 * This Pokemon is November on the Pokemon Horoscope in Pokemon Black and White.